H2N2V1, Main, Exploration, bibRecord, 001F07

Mass‐Spectrometric and GAUSSIAN2 Studies of the Diazene (HNNH) and Isodiazene (H2NN) Molecules and Their Radical Cations

Identifieur interne : 001F07 ( Main/Exploration ); précédent : 001F06; suivant : 001F08

Mass‐Spectrometric and GAUSSIAN2 Studies of the Diazene (HNNH) and Isodiazene (H2NN) Molecules and Their Radical Cations

Auteurs : Norman Goldberg [Allemagne] ; Max C. Holthausen [Allemagne] ; Jan Hrušák [Allemagne] ; Wolfram Koch [Allemagne] ; Helmut Schwarz [Allemagne]

Source :

Chemische Berichte [ 0009-2940 ] ; 1993-12.

RBID : ISTEX:65B11D6EFC3EFC27AF6945406E0A9BDEF2F7F143

Descripteurs français

Pascal (Inist)
- Activation par collision, Diazène, Etude expérimentale, Etude théorique, H N, Isomère, Méthode MO, Méthode ab initio, N2H2, Radical libre minéral cationique, Schéma fragmentation, Spectrométrie masse tandem, Surface potentiel.

English descriptors

Abstract

Collision experiments demonstrate that isodiazene (H2NN) and its radical cation are viable molecules in the gas phase. The mass‐spectrometric experiments are complemented by extensive ab‐initio MO calculations using the GAUSSIAN‐2 procedure in order to map out relevant parts of the potential energy surface of H2N2 (singlet) and H2N2+· (doublet).

Url:

https://api.istex.fr/ark:/67375/WNG-RZHJNS87-L/fulltext.pdf

DOI: 10.1002/cber.19931261227

Affiliations:

Le document en format XML

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<term>Fragmentation pattern</term>
<term>Inorganic radical cation</term>
<term>Isomer</term>
<term>MO method</term>
<term>Mass spectrometry MS/MS</term>
<term>Potential surface</term>
<term>Theoretical study</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Activation par collision</term>
<term>Diazène</term>
<term>Etude expérimentale</term>
<term>Etude théorique</term>
<term>H N</term>
<term>Isomère</term>
<term>Méthode MO</term>
<term>Méthode ab initio</term>
<term>N2H2</term>
<term>Radical libre minéral cationique</term>
<term>Schéma fragmentation</term>
<term>Spectrométrie masse tandem</term>
<term>Surface potentiel</term>
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<term>Cation</term>
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<term>Chem</term>
<term>Collision experiments</term>
<term>Collision gases</term>
<term>Collisional activation</term>
<term>Collisional activation mass spectrum</term>
<term>Diazene</term>
<term>Experimental findings</term>
<term>First characterization</term>
<term>Gaussian2 studies</term>
<term>Hnnh</term>
<term>Hydrazine sulfate</term>
<term>Isomer</term>
<term>Kcal</term>
<term>Koch</term>
<term>Mass spectrom</term>
<term>Mass spectrum</term>
<term>Neutral molecules</term>
<term>Phys</term>
<term>Potential energy surface</term>
<term>Radical cation</term>
<term>Radical cations</term>
<term>Recovery signal</term>
<term>Relative stabilities</term>
<term>Schwarz</term>
<term>Solitary molecules</term>
<term>Spectrom</term>
<term>Stable isomer</term>
<term>Theoretical results</term>
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<front><div type="abstract" xml:lang="en">Collision experiments demonstrate that isodiazene (H2NN) and its radical cation are viable molecules in the gas phase. The mass‐spectrometric experiments are complemented by extensive ab‐initio MO calculations using the GAUSSIAN‐2 procedure in order to map out relevant parts of the potential energy surface of H2N2 (singlet) and H2N2+· (doublet).</div>
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Mass‐Spectrometric and GAUSSIAN2 Studies of the Diazene (HNNH) and Isodiazene (H2NN) Molecules and Their Radical Cations

Mass‐Spectrometric and GAUSSIAN2 Studies of the Diazene (HNNH) and Isodiazene (H2NN) Molecules and Their Radical Cations

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

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